Transformation of 1,3-imidazolidine-2-thione (SC3H6N2) into (SC3H4N2–O–N2C3H4S)2− dianion chelated in [Pd{κ 3–S, O, S–(SC3H4N2–O–N2C3H4S)}(PPh3)]⋅CH3CN
نویسندگان
چکیده
منابع مشابه
Pentacarbonyl(imidazolidine-2-thione-κS)tungsten(0)
In the title complex, [W(C(3)H(6)N(2)S)(CO)(5)], the W atom displays an octa-hedral coordination with five CO mol-ecules and an imidazolidine-2-thione mol-ecule. The W(CO)(5) unit is coordinated by the cyclic thione ligand through a W-S dative bond. The W-S and C-S bond lengths are 2.599 (2) and 1.711 (9) Å, respectively. This last distance is significantly longer than that of free cyclic thio-...
متن کامل1,3-Bis(1-phenylethyl)imidazolidine-2-thione
The complete molecule of the title compound, C(19)H(22)N(2)S, is generated by crystallographic twofold symmetry with the C=S group lying on the rotation axis. The imidazolidine ring adopts a flattened twist conformation. The dihedral angle between the asymmetric part of the imidazolidine-2-thione fragment and the benzene ring is 89.49 (17)°.
متن کامل1,3-Bis(1-cyclohexylethyl)imidazolidine-2-thione
The complete mol-ecule of the title compound, C(19)H(34)N(2)S, is generated by crystallographic twofold symmetry, with the C=S group lying on the rotation axis. A short C-H⋯S contact occurs in the mol-ecule. The five-membered ring is twisted and the cyclo-hexyl ring adopts a chair conformation. The dihedral angle between the mean plane of the five-membered ring and the basal plane of the cyclo-...
متن کاملtrans-4,5-Dihydroxy-1,3-bis(4-methoxyphenyl)imidazolidine-2-thione
In the title compound, C(17)H(18)N(2)O(4)S, where one of the N-4-methoxy-phenyl fragments is disordered over two sets of sites, the five-membered ring exhibits a nearly half-chair conformation and the two hydroxyl groups lie on opposite sides of the five-membered ring. In the crystal, the mol-ecules are linked into sheets parallel to (100) via O-H⋯O and O-H⋯S hydrogen bonds.
متن کامل1-[5-(Dimethylamino)-1-naphthylsulfonyl]imidazolidine-2-thione
In the title mol-ecule, C(15)H(17)N(3)O(2)S(2), the dihedral angle between the naphthalene ring system and the imidazole ring is 89.63 (2)°. The crystal structure is stablized by weak inter-molecuar C-H⋯π and N-H⋯π inter-actions.
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ژورنال
عنوان ژورنال: Journal of Chemical Sciences
سال: 2017
ISSN: 0974-3626,0973-7103
DOI: 10.1007/s12039-017-1242-1